Rate constants and kinetic deuterium isotope effects for hydrogen atom abstraction from phenols by polyvinyl acetate radical

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Abstract

The primary kinetic deuterium isotope effect (PKIE) for the hydrogen atom abstraction from substituted phenols by polyvinyl acetate radical shows a large variation, and shows a maximum as a function of the reactivity of the compounds; the high values of PKIE may be attributed to tunnelling.

Original languageEnglish
Pages (from-to)252a
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
DOIs
Publication statusPublished - Jan 1 1975

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ASJC Scopus subject areas

  • Molecular Medicine

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