Rate and stereoselectivity changes during hydrogenation of N-heterocycles

Research output: Contribution to journalArticle

Abstract

High diastereoselectivities were obtained in the heterogeneous catalytic hydrogenation of chiral pyrrole and pyridine derivatives with complete conversion, in non-acidic medium. The products of the hydrogenations, secondary and tertiary amines act as catalyst modifiers, increasing the d.e. values in the last period of the reactions.

Original languageEnglish
Pages (from-to)109-115
Number of pages7
JournalReaction Kinetics and Catalysis Letters
Volume73
Issue number1
DOIs
Publication statusPublished - Dec 1 2001

Keywords

  • Catalyst modifier
  • Diastereoselective
  • Hydrogenation

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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