Raman spectroscopy of potassium acetate-intercalated kaolinites at liquid nitrogen temperature

Ray L. Frost, J. Kristóf, Jolene M. Schmidt, J. Theo Kloprogge

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Raman microscopy has been used to study low and high defect kaolinites and their potassium acetate intercalated complexes at 298 and 77 K. Raman spectroscopy shows significant differences in the spectra of the hydroxyl-stretching region of the two types of kaolinites, which is also reflected in the spectroscopy of the hydroxyl-stretching region of the intercalation complexes. Additional bands to the normally observed kaolinite hydroxyl stretching frequencies are observed for the low and high defect kaolinites at 3605 and 3602 cm-1 at 298 K. Upon cooling to liquid nitrogen temperature, these bands are observed at 3607 and 3604 cm-1, thus indicating a weakening of the hydrogen bond formed between the inner surface hydroxyls and the acetate ion. Upon cooling to liquid nitrogen temperature, the frequency of the inner hydroxyls shifted to lower frequencies. Collection of Raman spectra at liquid nitrogen temperature did not give better band separation compared to the room temperature spectra as the bands increased in width and shifted closer together.

Original languageEnglish
Pages (from-to)603-609
Number of pages7
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume57
Issue number3
DOIs
Publication statusPublished - Mar 1 2001

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Potassium Acetate
Liquid nitrogen
liquid nitrogen
Hydroxyl Radical
Potassium
Raman spectroscopy
acetates
potassium
Stretching
Cooling
cooling
Temperature
Defects
temperature
kaolinite
Kaolinite
defects
Kaolin
Intercalation
intercalation

ASJC Scopus subject areas

  • Spectroscopy

Cite this

Raman spectroscopy of potassium acetate-intercalated kaolinites at liquid nitrogen temperature. / Frost, Ray L.; Kristóf, J.; Schmidt, Jolene M.; Kloprogge, J. Theo.

In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Vol. 57, No. 3, 01.03.2001, p. 603-609.

Research output: Contribution to journalArticle

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