Radiolysis of liquid butylcycloalkanes: A stereochemical evaluation

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Abstract

Carbon skeleton decomposition reactions in the radiolysis of 14 n-, iso-, s- and t-butyl substituted cycloalkanes with 3-6 carbon atoms in the ring have been investigated and compared. The relationship between molecular structure and C-C rupture processes is discussed. Characteristic difference was found between the radiolysis of butylcycloalkanes with C3-C4 and C5-C6 rings: in the former case the rings, while in the latter the quarternary or tertiary carbons facilitate the decomposition. The results were interpreted on the basis of stereochemistry of the molecules.

Original languageEnglish
Pages (from-to)153-159
Number of pages7
JournalInternational Journal of Radiation Applications and Instrumentation. Part
Volume29
Issue number2
DOIs
Publication statusPublished - 1987

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radiolysis
evaluation
carbon
rings
liquids
decomposition
stereochemistry
musculoskeletal system
sands
molecular structure
atoms
molecules

Cite this

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title = "Radiolysis of liquid butylcycloalkanes: A stereochemical evaluation",
abstract = "Carbon skeleton decomposition reactions in the radiolysis of 14 n-, iso-, s- and t-butyl substituted cycloalkanes with 3-6 carbon atoms in the ring have been investigated and compared. The relationship between molecular structure and C-C rupture processes is discussed. Characteristic difference was found between the radiolysis of butylcycloalkanes with C3-C4 and C5-C6 rings: in the former case the rings, while in the latter the quarternary or tertiary carbons facilitate the decomposition. The results were interpreted on the basis of stereochemistry of the molecules.",
author = "G. F{\"o}ldi{\'a}k and L. Wojn{\'a}rovits and A. Kov{\'a}cs",
year = "1987",
doi = "10.1016/1359-0197(87)90051-8",
language = "English",
volume = "29",
pages = "153--159",
journal = "Radiation Physics and Chemistry",
issn = "0969-806X",
publisher = "Elsevier Limited",
number = "2",

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TY - JOUR

T1 - Radiolysis of liquid butylcycloalkanes

T2 - A stereochemical evaluation

AU - Földiák, G.

AU - Wojnárovits, L.

AU - Kovács, A.

PY - 1987

Y1 - 1987

N2 - Carbon skeleton decomposition reactions in the radiolysis of 14 n-, iso-, s- and t-butyl substituted cycloalkanes with 3-6 carbon atoms in the ring have been investigated and compared. The relationship between molecular structure and C-C rupture processes is discussed. Characteristic difference was found between the radiolysis of butylcycloalkanes with C3-C4 and C5-C6 rings: in the former case the rings, while in the latter the quarternary or tertiary carbons facilitate the decomposition. The results were interpreted on the basis of stereochemistry of the molecules.

AB - Carbon skeleton decomposition reactions in the radiolysis of 14 n-, iso-, s- and t-butyl substituted cycloalkanes with 3-6 carbon atoms in the ring have been investigated and compared. The relationship between molecular structure and C-C rupture processes is discussed. Characteristic difference was found between the radiolysis of butylcycloalkanes with C3-C4 and C5-C6 rings: in the former case the rings, while in the latter the quarternary or tertiary carbons facilitate the decomposition. The results were interpreted on the basis of stereochemistry of the molecules.

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U2 - 10.1016/1359-0197(87)90051-8

DO - 10.1016/1359-0197(87)90051-8

M3 - Article

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VL - 29

SP - 153

EP - 159

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

SN - 0969-806X

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