Quercetin 2,3-dioxygenase Mimicking Chemistry

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Abstract

Copper(I) and copper(II) flavonolate complexes have been isolated and characterized spectroscopically and structurally. Coordination of flavonol to copper through the 3-hydroxy and 4-carbonyl groups could be established by diffraction method. CuCl- and CuCl2-catalyzed oxygenation of flavonol in acetonitrile led only to a small extent to the depside or its hydrolysates. Copper(I) and copper(II) flavonolate catalyzed oxygenations gave exclusively quercetinase-like products in good yields.

Original languageEnglish
Pages (from-to)269-278
Number of pages10
JournalStudies in Surface Science and Catalysis
Volume66
Issue numberC
DOIs
Publication statusPublished - Jan 1 1991

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ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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