Quantitative assessment of organosulfates in size-segregated rural fine aerosol

H. Luḱacs, A. Gelencśer, A. Hoffer, G. Kiss, K. Horv́ath, Z. Hartýani

Research output: Contribution to journalArticle

57 Citations (Scopus)


Organosulfates have recently come into the focus of organic aerosol research as potentially important components of water-soluble secondary organic aerosol (SOA) which now dominate tropospheric fine aerosol. Their presence has been confirmed by the identification of sulfate esters of abundant biogenic carbonyl compounds in both smog chamber and continental aerosol. However, none of the studies have been able to determine the mass contribution of organosulfates to SOA. In this paper, as possibly the very first attempt to quantify organosulfates in ambient aerosol, we inferred the mass concentrations of organosulfates by concurrently determining mass concentrations of total sulfur, sulfate and methanesulfonate in rural fine aerosol using two highly sensitive analytical techniques. Although uncertainties were relatively large, we found that mass concentrations of organosulfates in water-soluble fine aerosol ranged from 0.02μ gSm-3 to 0.09μ gSm-3 yielding a mass contribution of 6-12% to bulk sulfur concentrations (or 6-14% to sulfate concentrations). The inferred size distribution of organosulfates suggested that they possibly form in heterogeneous reactions from semi-volatile carbonyl compounds with subsequent or concurrent condensation of gaseous sulfuric acid producing a refractory organic film on particle surfaces.

Original languageEnglish
Pages (from-to)231-238
Number of pages8
JournalAtmospheric Chemistry and Physics
Issue number1
Publication statusPublished - Jan 8 2009

ASJC Scopus subject areas

  • Atmospheric Science

Fingerprint Dive into the research topics of 'Quantitative assessment of organosulfates in size-segregated rural fine aerosol'. Together they form a unique fingerprint.

  • Cite this