Propagating fronts and morphological instabilities in a precipitation reaction

Brigitta Dúzs, István Lagzi, István Szalai

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4 Citations (Scopus)

Abstract

Precipitation processes are essential in many natural systems, especially in biomineralization and in geological pattern formation. We observe temporal oscillations in the total mass of the precipitate, the formation of propagating and annihilating waves, and morphological instabilities in a thin precipitation layer in a two-side-fed gel reactor containing the AlCl3/NaOH reaction-diffusion system. Contrary to the standard Liesegang patterns, these structures form in the lateral direction at the meeting of the counterpropagating diffusion fronts of the electrolytes. The two main ingredients of the system are the amphoteric precipitate and the cross gradient of the chemicals due to the fixed boundary conditions. Simulations with a four-variable precipitation/redissolution model qualitatively reproduce the oscillations in the total mass of the precipitate and point out the stratified three-dimensional structure of the precipitate.

Original languageEnglish
Pages (from-to)5460-5465
Number of pages6
JournalLangmuir
Volume30
Issue number19
DOIs
Publication statusPublished - May 20 2014

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ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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