Prins reaction of 2-oxabicyclo[3.3.0]oct-6-en-3-one and related derivatives

István Tömösközi, Lajos Gruber, E. Gács-Baitz

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Reaction of formaldehyde with the title olefinic lactone in acetic acid affords diacetate of 1,3-diol (2a) as the main product in 50 - 60% yield via regioselective trans-addition. Less favourable results were obtained with related bicyclic derivatives.

Original languageEnglish
Pages (from-to)10345-10352
Number of pages8
JournalTetrahedron
Volume48
Issue number47
DOIs
Publication statusPublished - Nov 20 1992

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Lactones
Acetic Acid
Formaldehyde
Derivatives

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Prins reaction of 2-oxabicyclo[3.3.0]oct-6-en-3-one and related derivatives. / Tömösközi, István; Gruber, Lajos; Gács-Baitz, E.

In: Tetrahedron, Vol. 48, No. 47, 20.11.1992, p. 10345-10352.

Research output: Contribution to journalArticle

Tömösközi, István ; Gruber, Lajos ; Gács-Baitz, E. / Prins reaction of 2-oxabicyclo[3.3.0]oct-6-en-3-one and related derivatives. In: Tetrahedron. 1992 ; Vol. 48, No. 47. pp. 10345-10352.
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