Preparation of mixed-acetal derivatives of carbohydrates by acetal-exchange reactions

András Lipták, Péter Fügedi, János Kerékgyártó, Pál Nánási

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Acetal-exchange reactions of 2,3-disubstituted gluco- and galacto-pyranoside derivatives with acetone dimethyl acetal and acetophenone dimethyl acetal gave the 6-O-(methoxydimethyl)methyl and the 6-O-(methoxymethylphenyl)methyl derivatives as the kinetic products. Formation of 6-O-(methoxydimethyl)methyl derivatives in transacetalation reactions was also demonstrated where cyclisation of the mixed acetal was impossible.

Original languageEnglish
Pages (from-to)225-231
Number of pages7
JournalCarbohydrate Research
Volume113
Issue number2
DOIs
Publication statusPublished - Mar 1 1983

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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