Preparation and characterization of parent and mixed-ligand complexes in 1,2-ethanediol-water-zinc sulphate systems. X-ray crystal structure of Zn(1,2-ethanediol)2(H2O)2(SO4)

I. Labadi, G. Bernat, L. Párkányí, G. Kenessey, G. Liptay

Research output: Contribution to journalArticle

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Abstract

Five mixed-ligand complexes containing 1,2-ethanediol, water and zinc sulphate were prepared. Two types of mixed-ligand complexes were observed on the basis of the thermal decomposition patterns and water bonding bands. Their thermal stabilities and IR spectra were investigated. The crystal structure of Zn(1,2-ethanediol)2(H2O)2(SO4) was determined by X-ray diffraction. Both 1,2-ethanediol and water coordinate to the zinc ion. The 1,2-ethanediol molecules are bonded to two zinc ions, forming a polymer network.

Original languageEnglish
Pages (from-to)2975-2981
Number of pages7
JournalPolyhedron
Volume11
Issue number23
DOIs
Publication statusPublished - 1992

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Zinc Sulfate
Ethylene Glycol
sulfates
Zinc
zinc
Crystal structure
Ligands
X-Rays
X rays
preparation
ligands
crystal structure
Water
water
x rays
Hot Temperature
Ions
thermal decomposition
ions
Pyrolysis

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Preparation and characterization of parent and mixed-ligand complexes in 1,2-ethanediol-water-zinc sulphate systems. X-ray crystal structure of Zn(1,2-ethanediol)2(H2O)2(SO4). / Labadi, I.; Bernat, G.; Párkányí, L.; Kenessey, G.; Liptay, G.

In: Polyhedron, Vol. 11, No. 23, 1992, p. 2975-2981.

Research output: Contribution to journalArticle

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