Polyurea/vinylester hybrid thermoset resins with in situ produced silicate filler: Preparation and static mechanical properties

J. Karger-Kocsis, S. Erdélyi, G. Nagy

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Proprietary polyurea-based thermosets were produced from polyisocyanate and water glass (WG) using a phosphate-type phase transfer catalyst. WG was dispersed in the polyisocyanate resulting in water-in-oil (W/O) type emulsion. The polyurea matrix, formed after crosslinking, contained the WG derived silicate in coarse particles showing a broad particle size distribution. The mean particle size of the silicate was markedly reduced and its distribution narrowed when the polyisocyanate was hybridized with a peroxide crosslinkable vinylester resin (VE) when the amount of the latter was

Original languageEnglish
Pages (from-to)853-859
Number of pages7
JournalJournal of Applied Polymer Science
Volume103
Issue number2
DOIs
Publication statusPublished - Jan 15 2007

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Silicates
Thermosets
Polyurethanes
Fillers
Resins
Mechanical properties
Water
Glass
Peroxides
Emulsions
Particle size analysis
Crosslinking
Particles (particulate matter)
Oils
Phosphates
Particle size
Catalysts
polyurea

Keywords

  • Failure
  • Flexure
  • Fracture mechanics
  • Polyisocyanate
  • Polysilicate
  • Polyurea hybrid resin
  • Vinylester resin

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Polyurea/vinylester hybrid thermoset resins with in situ produced silicate filler : Preparation and static mechanical properties. / Karger-Kocsis, J.; Erdélyi, S.; Nagy, G.

In: Journal of Applied Polymer Science, Vol. 103, No. 2, 15.01.2007, p. 853-859.

Research output: Contribution to journal › Article

Karger-Kocsis, J, Erdélyi, S & Nagy, G 2007, 'Polyurea/vinylester hybrid thermoset resins with in situ produced silicate filler: Preparation and static mechanical properties', Journal of Applied Polymer Science, vol. 103, no. 2, pp. 853-859. https://doi.org/10.1002/app.25200
Karger-Kocsis J, Erdélyi S, Nagy G. Polyurea/vinylester hybrid thermoset resins with in situ produced silicate filler: Preparation and static mechanical properties. Journal of Applied Polymer Science. 2007 Jan 15;103(2):853-859. https://doi.org/10.1002/app.25200
Karger-Kocsis, J. ; Erdélyi, S. ; Nagy, G. / Polyurea/vinylester hybrid thermoset resins with in situ produced silicate filler : Preparation and static mechanical properties. In: Journal of Applied Polymer Science. 2007 ; Vol. 103, No. 2. pp. 853-859.
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