Polymer-bound osmium oxide catalysts

Wolfgang A. Herrmann, Roland M. Kratzer, Janet Blümel, Holger B. Friedrich, Richard W. Fischer, David C. Apperley, J. Mink, O. Berkesi

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Polymer-supported oxidic osmium catalysts based on cross-linked poly(4-vinyl pyridine) were synthesized by various routes and characterized by a number of physical techniques (Raman, IR, XPS, 13C and 15N solid-state NMR spectroscopy). Model compounds of type Os2O6L4 (L = pyridine, 4-iso-propyl pyridine, and 4-tert-butyl pyridine) were obtained under the conditions of the catalyst synthesis. The catalytic systems were successful in the dihydroxylation of alkenes.

Original languageEnglish
Pages (from-to)197-205
Number of pages9
JournalJournal of Molecular Catalysis A: Chemical
Volume120
Issue number1-3
DOIs
Publication statusPublished - Jun 13 1997

Fingerprint

Osmium
osmium
Pyridine
Oxides
pyridines
Polymers
catalysts
Catalysts
oxides
polymers
Alkenes
Nuclear magnetic resonance spectroscopy
alkenes
Olefins
X ray photoelectron spectroscopy
routes
solid state
nuclear magnetic resonance
pyridine
synthesis

Keywords

  • Alkenes
  • Dihydroxylation
  • Osmium
  • Supported catalyst

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Herrmann, W. A., Kratzer, R. M., Blümel, J., Friedrich, H. B., Fischer, R. W., Apperley, D. C., ... Berkesi, O. (1997). Polymer-bound osmium oxide catalysts. Journal of Molecular Catalysis A: Chemical, 120(1-3), 197-205. https://doi.org/10.1016/S1381-1169(96)00419-0

Polymer-bound osmium oxide catalysts. / Herrmann, Wolfgang A.; Kratzer, Roland M.; Blümel, Janet; Friedrich, Holger B.; Fischer, Richard W.; Apperley, David C.; Mink, J.; Berkesi, O.

In: Journal of Molecular Catalysis A: Chemical, Vol. 120, No. 1-3, 13.06.1997, p. 197-205.

Research output: Contribution to journalArticle

Herrmann, WA, Kratzer, RM, Blümel, J, Friedrich, HB, Fischer, RW, Apperley, DC, Mink, J & Berkesi, O 1997, 'Polymer-bound osmium oxide catalysts', Journal of Molecular Catalysis A: Chemical, vol. 120, no. 1-3, pp. 197-205. https://doi.org/10.1016/S1381-1169(96)00419-0
Herrmann WA, Kratzer RM, Blümel J, Friedrich HB, Fischer RW, Apperley DC et al. Polymer-bound osmium oxide catalysts. Journal of Molecular Catalysis A: Chemical. 1997 Jun 13;120(1-3):197-205. https://doi.org/10.1016/S1381-1169(96)00419-0
Herrmann, Wolfgang A. ; Kratzer, Roland M. ; Blümel, Janet ; Friedrich, Holger B. ; Fischer, Richard W. ; Apperley, David C. ; Mink, J. ; Berkesi, O. / Polymer-bound osmium oxide catalysts. In: Journal of Molecular Catalysis A: Chemical. 1997 ; Vol. 120, No. 1-3. pp. 197-205.
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