Polar effect in the reaction of CH3O with HBr

Edit Farkas, Gergely Kovács, Krisztina Imrik, István Szilágyi, S. Dóbé, Ferenc Márta

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The discharge flow method with laser induced fluorescence detection of CH3O was applied to determine the rate constant, k1, for the reaction CH3O + HBr → products (1) k1 (298 K) = (8.41 σ 0.80(1σ)) 1011 cm3 mol-1 s-1. The unusually large k1 value was explained by the polar nature of the transition state of the reaction.

Original languageEnglish
Pages (from-to)315-320
Number of pages6
JournalReaction Kinetics and Catalysis Letters
Volume83
Issue number2
DOIs
Publication statusPublished - 2004

Fingerprint

Rate constants
Fluorescence
Lasers
laser induced fluorescence
products

Keywords

  • Cho
  • Hbr
  • Rate constant

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Polar effect in the reaction of CH3O with HBr. / Farkas, Edit; Kovács, Gergely; Imrik, Krisztina; Szilágyi, István; Dóbé, S.; Márta, Ferenc.

In: Reaction Kinetics and Catalysis Letters, Vol. 83, No. 2, 2004, p. 315-320.

Research output: Contribution to journalArticle

Farkas, E, Kovács, G, Imrik, K, Szilágyi, I, Dóbé, S & Márta, F 2004, 'Polar effect in the reaction of CH3O with HBr', Reaction Kinetics and Catalysis Letters, vol. 83, no. 2, pp. 315-320. https://doi.org/10.1023/B:REAC.0000046092.84948.e0
Farkas, Edit ; Kovács, Gergely ; Imrik, Krisztina ; Szilágyi, István ; Dóbé, S. ; Márta, Ferenc. / Polar effect in the reaction of CH3O with HBr. In: Reaction Kinetics and Catalysis Letters. 2004 ; Vol. 83, No. 2. pp. 315-320.
@article{f0875c55d75d4a45a806f11c983804d8,
title = "Polar effect in the reaction of CH3O with HBr",
abstract = "The discharge flow method with laser induced fluorescence detection of CH3O was applied to determine the rate constant, k1, for the reaction CH3O + HBr → products (1) k1 (298 K) = (8.41 σ 0.80(1σ)) 1011 cm3 mol-1 s-1. The unusually large k1 value was explained by the polar nature of the transition state of the reaction.",
keywords = "Cho, Hbr, Rate constant",
author = "Edit Farkas and Gergely Kov{\'a}cs and Krisztina Imrik and Istv{\'a}n Szil{\'a}gyi and S. D{\'o}b{\'e} and Ferenc M{\'a}rta",
year = "2004",
doi = "10.1023/B:REAC.0000046092.84948.e0",
language = "English",
volume = "83",
pages = "315--320",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
issn = "1878-5190",
publisher = "Springer Netherlands",
number = "2",

}

TY - JOUR

T1 - Polar effect in the reaction of CH3O with HBr

AU - Farkas, Edit

AU - Kovács, Gergely

AU - Imrik, Krisztina

AU - Szilágyi, István

AU - Dóbé, S.

AU - Márta, Ferenc

PY - 2004

Y1 - 2004

N2 - The discharge flow method with laser induced fluorescence detection of CH3O was applied to determine the rate constant, k1, for the reaction CH3O + HBr → products (1) k1 (298 K) = (8.41 σ 0.80(1σ)) 1011 cm3 mol-1 s-1. The unusually large k1 value was explained by the polar nature of the transition state of the reaction.

AB - The discharge flow method with laser induced fluorescence detection of CH3O was applied to determine the rate constant, k1, for the reaction CH3O + HBr → products (1) k1 (298 K) = (8.41 σ 0.80(1σ)) 1011 cm3 mol-1 s-1. The unusually large k1 value was explained by the polar nature of the transition state of the reaction.

KW - Cho

KW - Hbr

KW - Rate constant

UR - http://www.scopus.com/inward/record.url?scp=7544230779&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=7544230779&partnerID=8YFLogxK

U2 - 10.1023/B:REAC.0000046092.84948.e0

DO - 10.1023/B:REAC.0000046092.84948.e0

M3 - Article

VL - 83

SP - 315

EP - 320

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

SN - 1878-5190

IS - 2

ER -