Platinum(II) complexes of 2-alkoxy-dibenzo[c.e][1,2]oxaphosphorines

G. Keglevich, Andrea Kerényi, Beatrix Mayer, T. Körtvélyesi, K. Ludányi

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17 Citations (Scopus)

Abstract

2-Alkoxy-dibenzo[c.e][1,2]oxaphosphorines were prepared by the reaction of chloro-dibenzooxaphosphorine with alcohols and were converted to the cyclic phosphonates by oxidation and to the corresponding phosphonous boranes by reaction with borane-dimethylsulfide. Interaction of the alkoxy- dibenzooxaphosphorines with dichlorodibenzonitrileplatinum led to bis(dibenzooxaphosphorino)dichloroplatinum complexes exhibiting the P-ligands in the cis disposition. Relative energetics for the prepared cis and the theoretically possible trans isomers of the complexes along with their stereostructures were investigated by quantum chemical calculations.

Original languageEnglish
Pages (from-to)505-510
Number of pages6
JournalTransition Metal Chemistry
Volume33
Issue number4
DOIs
Publication statusPublished - May 2008

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Boranes
Platinum
Isomers
Alcohols
Ligands
Organophosphonates
Oxidation
alkoxyl radical
dimethyl sulfide

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Platinum(II) complexes of 2-alkoxy-dibenzo[c.e][1,2]oxaphosphorines. / Keglevich, G.; Kerényi, Andrea; Mayer, Beatrix; Körtvélyesi, T.; Ludányi, K.

In: Transition Metal Chemistry, Vol. 33, No. 4, 05.2008, p. 505-510.

Research output: Contribution to journalArticle

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