Picosecond time-resolved X-ray emission spectroscopy: Ultrafast spin-state determination in an iron complex

G. Vankó, Pieter Glatzel, Van Thai Pham, Rafael Abela, Daniel Grolimund, Camelia N. Borca, Steven L. Johnson, Christopher J. Milne, Christian Bressler

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

(Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy)3]2+ (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.

Original languageEnglish
Pages (from-to)5910-5912
Number of pages3
JournalAngewandte Chemie - International Edition
Volume49
Issue number34
DOIs
Publication statusPublished - Aug 9 2010

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Momentum
Iron
Geometry
X-Ray Emission Spectrometry

Keywords

  • Femtochemistry
  • Iron
  • Spin crossover
  • Time-resolved spectroscopy
  • X-ray emission spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex. / Vankó, G.; Glatzel, Pieter; Pham, Van Thai; Abela, Rafael; Grolimund, Daniel; Borca, Camelia N.; Johnson, Steven L.; Milne, Christopher J.; Bressler, Christian.

In: Angewandte Chemie - International Edition, Vol. 49, No. 34, 09.08.2010, p. 5910-5912.

Research output: Contribution to journalArticle

Vankó, G, Glatzel, P, Pham, VT, Abela, R, Grolimund, D, Borca, CN, Johnson, SL, Milne, CJ & Bressler, C 2010, 'Picosecond time-resolved X-ray emission spectroscopy: Ultrafast spin-state determination in an iron complex', Angewandte Chemie - International Edition, vol. 49, no. 34, pp. 5910-5912. https://doi.org/10.1002/anie.201000844
Vankó, G. ; Glatzel, Pieter ; Pham, Van Thai ; Abela, Rafael ; Grolimund, Daniel ; Borca, Camelia N. ; Johnson, Steven L. ; Milne, Christopher J. ; Bressler, Christian. / Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 34. pp. 5910-5912.
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