Photolysis of the cycloadduct of a 1,2-dihydrophosphinine oxide with N-phenylmaleimide in the presence of protic species

New aspects on the mechanism of the fragmentation of a 2-phosphabicyclo[2.2.2]octene

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Phosphabicyclo[2.2.2]octene 2 is useful in the UV light mediated phosphorylation of protic species. Experiments suggest that the fragmentation takes place according to concurrent EA and AE mechanisms.

Original languageEnglish
Pages (from-to)49-53
Number of pages5
JournalJournal of Organometallic Chemistry
Volume570
Issue number1
Publication statusPublished - Nov 10 1998

Fingerprint

phosphorylation
Phosphorylation
Photolysis
Ultraviolet Rays
Ultraviolet radiation
Oxides
photolysis
fragmentation
oxides
Experiments
N-phenylmaleimide

Keywords

  • 2-Phosphabicyclo[2.2.2]octene 2-oxide
  • Fragmentation
  • Mechanism
  • Phosphorylation

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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title = "Photolysis of the cycloadduct of a 1,2-dihydrophosphinine oxide with N-phenylmaleimide in the presence of protic species: New aspects on the mechanism of the fragmentation of a 2-phosphabicyclo[2.2.2]octene",
abstract = "Phosphabicyclo[2.2.2]octene 2 is useful in the UV light mediated phosphorylation of protic species. Experiments suggest that the fragmentation takes place according to concurrent EA and AE mechanisms.",
keywords = "2-Phosphabicyclo[2.2.2]octene 2-oxide, Fragmentation, Mechanism, Phosphorylation",
author = "Gy{\"o}rgy Keglevich and Kinga Steinhauser and Krisztina Lud{\'a}nyi and Toke, {L{\'a}sl{\'o} R.}",
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AU - Keglevich, György

AU - Steinhauser, Kinga

AU - Ludányi, Krisztina

AU - Toke, Lásló R.

PY - 1998/11/10

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KW - Mechanism

KW - Phosphorylation

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