Photolysis of 7-(2,4,6-trialkylphenyl-)7-phosphanorbornene 7-oxides in the presence of protic species

G. Keglevich, K. Ludányi, Louis D. Quin

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Irradiation of 7-(2,4,6-trialkylphenyl-)7-phosphanorbornene 7-oxides at 254 nm in the presence of alcohols or water led to H-phosphinic acid derivatives. The experimental data are consistent with the mechanism established earlier for P-phenyl derivatives, involving a five-coordinate adduct from the interaction of the phosphanorbornene and the protic species which then fragments. There is no evidence that the larger substituent allowed a competing reaction to occur where the first step is unimolecular fragmentation to a two-coordinate phosphoryl species.

Original languageEnglish
Pages (from-to)135-137
Number of pages3
JournalHeteroatom Chemistry
Volume8
Issue number2
Publication statusPublished - 1997

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Photolysis
Oxides
Phosphinic Acids
Derivatives
Alcohols
Irradiation
Water
Phenyl-P adhesion promoting monomer

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Photolysis of 7-(2,4,6-trialkylphenyl-)7-phosphanorbornene 7-oxides in the presence of protic species. / Keglevich, G.; Ludányi, K.; Quin, Louis D.

In: Heteroatom Chemistry, Vol. 8, No. 2, 1997, p. 135-137.

Research output: Contribution to journalArticle

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