Photoelectron spectroscopic investigation of perimidine derivatives

L. Nyulászi, T. Pasinszki, J. Réffy, T. Veszprémi, J. Fabian, W. Thiel

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The Hel UPS spectra of acetamidine, perimidine, and four 2-substituted perimidine derivatives have been recorded and interpreted using ab initio and MNDO quantum-chemical calculations. A large interaction between the naphthalene and amidine fragment was concluded from the lowest ionization energy. The color-determining band of these compounds is strongly affected by the intramolecular charge-transfer transitions, which are of low energy because of the low ionization energy of the perimidine moiety.

Original languageEnglish
Pages (from-to)367-370
Number of pages4
JournalStructural Chemistry
Volume1
Issue number4
DOIs
Publication statusPublished - Jul 1990

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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