Penning ionization electron spectroscopy and CNDO/S calculations have been successfully applied to the analyses of the UV photoelectron spectra of some silazanes. The relative intensities of the lone pair bands are enhanced in the Penning spectra compared with those in the UV photoelectron spectra. The intensity differences between the two spectra give useful informations for the investigation of the σ-electron systems.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry