Photodissociation dynamics of the LiF molecule: Two- and three-state descriptions

A. Tóth, A. Csehi, G. Halász, A. Vibók

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Abstract

The photodissociation of the lithium fluoride molecule gathered much attention lately. Theoretical works treating this subject usually consider the 1Σ+1 and 2Σ+1 electronic states, which are coupled nonadiabatically. As a continuation of a previous work, we intend to highlight the importance of the 1Π1 state by investigating the kinetic energy and angular distribution of the photofragments. Besides, our results pointed out the importance of the molecular rotation.

Original languageEnglish
Article number043424
JournalPhysical Review A
Volume99
Issue number4
DOIs
Publication statusPublished - Apr 24 2019

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ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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