Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates

Zita Rádai, Viktória Hodula, Nóra Zsuzsa Kiss, János Kóti, G. Keglevich

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Abstract

The reaction of dimethyl (1-aryl-1-hydroxymethyl)phosphonates with 1-chloro-3-phospholene 1-oxides, diphenylphosphinic chloride or diphenyl chloridophosphonate affords the corresponding (1-phosphoryloxymethyl)phosphonates. The products with two different >P(O)– moieties exhibit characteristic δ P shifts and 3 J P,P couplings in the 31 P NMR spectra.

Original languageEnglish
Pages (from-to)153-154
Number of pages2
JournalMendeleev Communications
Volume29
Issue number2
DOIs
Publication statusPublished - Mar 1 2019

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ASJC Scopus subject areas

  • Chemistry(all)

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