Phosphorus-Containing Polycyclic Aromatic Hydrocarbons

Rózsa Szűcs, Pierre Antoine Bouit, László Nyulászi, Muriel Hissler

Research output: Contribution to journalReview article

27 Citations (Scopus)

Abstract

Polycyclic aromatic hydrocarbons (PAHs) are highly appealing functional materials in the field of molecular electronics. In particular, molecular engineering of these derivatives by using organic chemistry is a powerful method to tune their properties from the point of view of the band gap and supramolecular assemblies. Another way to achieve such control is to take advantage of the specific reactivity of heteroatoms placed within the sp2-carbon framework. This strategy has been successfully applied to nitrogen, sulfur and boron. In this review, examples of phosphorus-containing PAHs and the effect of the phosphorus environment on the electronic properties from both experimental and theoretical points of view are discussed.

Original languageEnglish
Pages (from-to)2618-2630
Number of pages13
JournalChemPhysChem
Volume18
Issue number19
DOIs
Publication statusPublished - Oct 6 2017

Keywords

  • aromaticity
  • doping
  • hydrocarbons
  • phosphorus
  • polycycles

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Physical and Theoretical Chemistry

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