Phosphorus-31 magnetic relaxation of phosphocreatine in solution

R. Gáspár, W. S. Brey, E. R. Andrew

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Measurements have been made of the longitudinal phosphorus-31 magnetic relaxation of phosphocreatine in H2O and D2O solutions from 278 to 333 K at 121.5 and at 40.5 MHz. The phosphorus-31 spin-lattice relaxation of phosphocreatine is dominated by intermolecular and intramolecular dipolar and chemical-shift anisotropy interactions. The relative contribution of the two interactions to the spin-lattice relaxation changes with NMR frequency. Activation energies characterizing the solution dynamics of the phosphocreatine molecule in H2O and D2O are 15.4±1.1 and 14.6±1.0 kJ/mol, respectively.

Original languageEnglish
Pages (from-to)17-20
Number of pages4
JournalChemical Physics Letters
Volume184
Issue number1-3
DOIs
Publication statusPublished - Sep 20 1991

Fingerprint

Magnetic relaxation
Phosphocreatine
magnetic relaxation
spin-lattice relaxation
Phosphorus
phosphorus
Spin-lattice relaxation
chemical equilibrium
Chemical shift
interactions
activation energy
nuclear magnetic resonance
anisotropy
Anisotropy
Activation energy
Nuclear magnetic resonance
molecules
Molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Phosphorus-31 magnetic relaxation of phosphocreatine in solution. / Gáspár, R.; Brey, W. S.; Andrew, E. R.

In: Chemical Physics Letters, Vol. 184, No. 1-3, 20.09.1991, p. 17-20.

Research output: Contribution to journalArticle

Gáspár, R. ; Brey, W. S. ; Andrew, E. R. / Phosphorus-31 magnetic relaxation of phosphocreatine in solution. In: Chemical Physics Letters. 1991 ; Vol. 184, No. 1-3. pp. 17-20.
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