Phosphinerhodium complexes as homogeneous catalysts. X. Homogeneous hydrogenation of ketones using phosphinerhodium catalysts modified with triethylamine

Bálint Heil, Szilárd Törös, J. Bakos, Lászlo Markó

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Triethylamine significantly increases the catalytic activity in ketone hydrogenation of rhodium complexes containing aromatic phosphines. If chiral phosphines are used, optical yields depend on the amount of triethylamine added, suggesting that several catalytically active species are involved.

Original languageEnglish
Pages (from-to)229-232
Number of pages4
JournalJournal of Organometallic Chemistry
Volume175
Issue number2
DOIs
Publication statusPublished - Aug 21 1979

Fingerprint

Phosphines
Hydrogenation
Rhodium
Ketones
phosphines
ketones
hydrogenation
Catalyst activity
catalysts
Catalysts
rhodium
catalytic activity
triethylamine

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Phosphinerhodium complexes as homogeneous catalysts. X. Homogeneous hydrogenation of ketones using phosphinerhodium catalysts modified with triethylamine. / Heil, Bálint; Törös, Szilárd; Bakos, J.; Markó, Lászlo.

In: Journal of Organometallic Chemistry, Vol. 175, No. 2, 21.08.1979, p. 229-232.

Research output: Contribution to journalArticle

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