Particulate carbon in precipitation at European background sites

Mário Cerqueira, Casimiro Pio, Michel Legrand, Hans Puxbaum, Anne Kasper-Giebl, Joana Afonso, Susanne Preunkert, András Gelencsér, Paulo Fialho

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48 Citations (Scopus)

Abstract

The particulate carbon content of precipitation was investigated in samples collected at five background sites located over a west-east European transect, from the Azores, in the mid-Atlantic Ocean, to the Hungarian plain, in central Europe. Sampling was performed on an event basis and the particulate carbon (elemental carbon, EC, and water insoluble organic carbon, WIOC) content was concentrated on quartz filters for the subsequent analysis by a thermal optical method in order to separate the EC and WIOC fractions. The average EC concentrations range from low values at the Azores (2.8±4.3 μg C L-1) and at the high mountain site of Sonnblick (5.2±3.7 μg C L-1) to high values at the more inland sites of Schauinsland (28±38 μg C L-1) and K-Puszta (24±24 μg C L-1). The average WIOC concentrations range from 98±56 μg C L-1 at the coastal site of Aveiro and 113±78 μg C L-1 at the Azores to 358±194 μg C L-1 at the continental site of K-Puszta. These results are discussed in terms of factors affecting the spatial distribution of particulate carbon, such as emissions from surrounding areas and prevalent meteorological conditions. EC is found to be a minor contributor to total particulate carbon present in rain and snow samples (from 2.5% to 15%). This is particularly true at the remotes sites, where the EC contribution to total particulate carbon is <6.5%, consistent with a negligible impact of anthropogenic combustions locally. The EC and WIOC scavenging ratios were estimated and compared with those of sulfate, also evaluated at the same sampling sites. The results indicated that EC is removed from the atmosphere by wet deposition less efficiently than WIOC, and in turn this species is removed less efficiently than sulfate.

Original languageEnglish
Pages (from-to)51-61
Number of pages11
JournalJournal of Aerosol Science
Volume41
Issue number1
DOIs
Publication statusPublished - Jan 2010

Keywords

  • Background atmosphere
  • Elemental carbon
  • Organic carbon
  • Particulate matter
  • Precipitation
  • Scavenging ratios
  • Wet deposition

ASJC Scopus subject areas

  • Environmental Engineering
  • Pollution
  • Mechanical Engineering
  • Fluid Flow and Transfer Processes
  • Atmospheric Science

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  • Cite this

    Cerqueira, M., Pio, C., Legrand, M., Puxbaum, H., Kasper-Giebl, A., Afonso, J., Preunkert, S., Gelencsér, A., & Fialho, P. (2010). Particulate carbon in precipitation at European background sites. Journal of Aerosol Science, 41(1), 51-61. https://doi.org/10.1016/j.jaerosci.2009.08.002