Palladium-platinum powder catalysts manufactured by colloid synthesis: II. Characterization and catalytic tests after oxidizing and reducing treatment

N. Gyrffy, L. Tóth, M. Bartók, J. Ocskó, U. Wild, R. Schlögl, D. Teschner, Z. Paál

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Unsupported Pd, Pt and PdPt bimetallic catalysts were prepared in different atomic ratios using methods of colloid chemistry. They were characterized by XPS, UPS and TEM. Four subsequent treatments with O2 and H 2 up to T = 603 K were applied in the preparation chamber of the electron spectrometer and before the catalytic runs. Platinum strongly hindered the oxidation of palladium in the bimetallic samples indicating an alloying of the two components. The H2 treatment after O2 led to rather clean metals. These treatments up to 603 K decreased the Pt enrichment near to the surface found by XPS, destroying presumably the Pt islands on the surface of a Pd-rich matrix. The particle composition approached thus a homogeneous metal mixture. The catalytic behavior was tested in the hydrogenative ring opening reaction of cis- and trans-methyl-ethyl-cyclopropane (MECP) at 373 K. The product ratios 2-methylpentane/3-methylpentane (2MP/3MP) and 2-methylpentane/n-hexane (2MP/nH) were used to characterize the ring-opening pattern of the samples. The bimetallic catalysts revealed higher activity and completely different selectivities than the monometallic Pt and Pd. Moreover, the 2MP/3MP ratio from trans-MECP and 2MP/nH ratio from cis-MECP increased as the surface Pt enrichment decreased. PdPt catalysts were cleaner than Pd or Pt, their activity higher and selectivity closer to random CC rupture, due, very likely, to the presence of active Pd-Pt ensembles.

Original languageEnglish
Pages (from-to)102-110
Number of pages9
JournalJournal of Molecular Catalysis A: Chemical
Volume238
Issue number1-2
DOIs
Publication statusPublished - Sep 1 2005

Keywords

  • Bimetallic catalyst
  • Cyclopropane ring opening
  • Pd
  • Pt
  • UPS
  • XPS

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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