Palladium-catalysed transfer hydrogenation of aromatic nitro compounds - An unusual chain elongation

János Németh, Árpád Kiss, Z. Hell

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Aromatic nitro compounds are reduced via transfer hydrogenation in the presence of palladium on magnesium-lanthanum mixed oxide support in ethanol yielding the corresponding amines. With several acetophenone derivatives, the reduction was accompanied by chain elongation whilst the carbonyl group remained intact.

Original languageEnglish
Pages (from-to)6094-6096
Number of pages3
JournalTetrahedron Letters
Volume54
Issue number45
DOIs
Publication statusPublished - Nov 6 2013

Fingerprint

Nitro Compounds
Lanthanum
Hydrogenation
Palladium
Oxides
Magnesium
Amines
Elongation
Ethanol
Derivatives
acetophenone
lanthanum oxide

Keywords

  • Chain elongation
  • Heterogeneous catalysis
  • Palladium
  • Transfer hydrogenation

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Palladium-catalysed transfer hydrogenation of aromatic nitro compounds - An unusual chain elongation. / Németh, János; Kiss, Árpád; Hell, Z.

In: Tetrahedron Letters, Vol. 54, No. 45, 06.11.2013, p. 6094-6096.

Research output: Contribution to journalArticle

@article{751d5f784c9f4efcaf18d186f0503c62,
title = "Palladium-catalysed transfer hydrogenation of aromatic nitro compounds - An unusual chain elongation",
abstract = "Aromatic nitro compounds are reduced via transfer hydrogenation in the presence of palladium on magnesium-lanthanum mixed oxide support in ethanol yielding the corresponding amines. With several acetophenone derivatives, the reduction was accompanied by chain elongation whilst the carbonyl group remained intact.",
keywords = "Chain elongation, Heterogeneous catalysis, Palladium, Transfer hydrogenation",
author = "J{\'a}nos N{\'e}meth and {\'A}rp{\'a}d Kiss and Z. Hell",
year = "2013",
month = "11",
day = "6",
doi = "10.1016/j.tetlet.2013.08.123",
language = "English",
volume = "54",
pages = "6094--6096",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "45",

}

TY - JOUR

T1 - Palladium-catalysed transfer hydrogenation of aromatic nitro compounds - An unusual chain elongation

AU - Németh, János

AU - Kiss, Árpád

AU - Hell, Z.

PY - 2013/11/6

Y1 - 2013/11/6

N2 - Aromatic nitro compounds are reduced via transfer hydrogenation in the presence of palladium on magnesium-lanthanum mixed oxide support in ethanol yielding the corresponding amines. With several acetophenone derivatives, the reduction was accompanied by chain elongation whilst the carbonyl group remained intact.

AB - Aromatic nitro compounds are reduced via transfer hydrogenation in the presence of palladium on magnesium-lanthanum mixed oxide support in ethanol yielding the corresponding amines. With several acetophenone derivatives, the reduction was accompanied by chain elongation whilst the carbonyl group remained intact.

KW - Chain elongation

KW - Heterogeneous catalysis

KW - Palladium

KW - Transfer hydrogenation

UR - http://www.scopus.com/inward/record.url?scp=84885313855&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84885313855&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2013.08.123

DO - 10.1016/j.tetlet.2013.08.123

M3 - Article

AN - SCOPUS:84885313855

VL - 54

SP - 6094

EP - 6096

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 45

ER -