Oxoiron(iv)-mediated Baeyer-Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes

Dóra Lakk-Bogáth, Gábor Speier, József Kaizer

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer-Villiger oxidation of cyclohexanones by dioxygen with cooxidation of various aldehydes, including the kinetics of the formation and the reactivity of the trapped and spectroscopically characterized oxoiron(iv) intermediate.

Original languageEnglish
Pages (from-to)8245-8248
Number of pages4
JournalNew Journal of Chemistry
Volume39
Issue number11
DOIs
Publication statusPublished - Sep 4 2015

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

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