Oxoiron(iv)-mediated Baeyer-Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes

Dóra Lakk-Bogáth, G. Speier, J. Kaizer

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer-Villiger oxidation of cyclohexanones by dioxygen with cooxidation of various aldehydes, including the kinetics of the formation and the reactivity of the trapped and spectroscopically characterized oxoiron(iv) intermediate.

Original languageEnglish
Pages (from-to)8245-8248
Number of pages4
JournalNew Journal of Chemistry
Volume39
Issue number11
DOIs
Publication statusPublished - Sep 4 2015

Fingerprint

Cyclohexanones
Aldehydes
Amines
Oxygen
Oxidation
Kinetics
Communication
perchlorate

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

Cite this

Oxoiron(iv)-mediated Baeyer-Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes. / Lakk-Bogáth, Dóra; Speier, G.; Kaizer, J.

In: New Journal of Chemistry, Vol. 39, No. 11, 04.09.2015, p. 8245-8248.

Research output: Contribution to journalArticle

@article{1a77bcbcbecc4717935bc9ab09c39983,
title = "Oxoiron(iv)-mediated Baeyer-Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes",
abstract = "In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer-Villiger oxidation of cyclohexanones by dioxygen with cooxidation of various aldehydes, including the kinetics of the formation and the reactivity of the trapped and spectroscopically characterized oxoiron(iv) intermediate.",
author = "D{\'o}ra Lakk-Bog{\'a}th and G. Speier and J. Kaizer",
year = "2015",
month = "9",
day = "4",
doi = "10.1039/c5nj02093j",
language = "English",
volume = "39",
pages = "8245--8248",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "11",

}

TY - JOUR

T1 - Oxoiron(iv)-mediated Baeyer-Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes

AU - Lakk-Bogáth, Dóra

AU - Speier, G.

AU - Kaizer, J.

PY - 2015/9/4

Y1 - 2015/9/4

N2 - In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer-Villiger oxidation of cyclohexanones by dioxygen with cooxidation of various aldehydes, including the kinetics of the formation and the reactivity of the trapped and spectroscopically characterized oxoiron(iv) intermediate.

AB - In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer-Villiger oxidation of cyclohexanones by dioxygen with cooxidation of various aldehydes, including the kinetics of the formation and the reactivity of the trapped and spectroscopically characterized oxoiron(iv) intermediate.

UR - http://www.scopus.com/inward/record.url?scp=84946042182&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84946042182&partnerID=8YFLogxK

U2 - 10.1039/c5nj02093j

DO - 10.1039/c5nj02093j

M3 - Article

VL - 39

SP - 8245

EP - 8248

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 11

ER -