Oxo transfer reactions of Mo(Vl) complexes to phosphines and phosphites

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The oxygenation reactions of aldehydes, tertiary phosphines and phosphites catalyzed by the cis-dioxomolybdenum(VI)-ethyl-L-cysteinate complex were studied. The reaction with aldehydes seems to have a radical character and that with phosphines and phorphites involves an oxo transfer from molybdenu m to trivalent phosphorus. Some attempts were made to find a correlation between reactivity and structure of the substrates.

Original languageEnglish
Pages (from-to)139-141
Number of pages3
JournalInorganica Chimica Acta
Volume32
Issue numberC
DOIs
Publication statusPublished - 1979

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Phosphines
Phosphites
Aldehydes
aldehydes
phosphines
Oxygenation
oxygenation
Phosphorus
phosphorus
reactivity
Substrates

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Oxo transfer reactions of Mo(Vl) complexes to phosphines and phosphites. / Speier, G.

In: Inorganica Chimica Acta, Vol. 32, No. C, 1979, p. 139-141.

Research output: Contribution to journalArticle

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