Oxidative dehydrogenation of n-butenes: Product effect in the reactions over tin-antimony mixed oxides

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The addition of possible oxidation and/or isomerization products (butadiene, water, isomeric n-butenes) resulted in neither promotion nor inhibition in the oxidative dehydrogenation of n-butenes over tin-antimony mixed oxide catalysts. On the basis of these and other information on the influence of products an interpretation has been given to complete the reaction mechanism more realistic than those based on previous experimental results.

Original languageEnglish
Pages (from-to)221-226
Number of pages6
JournalReaction Kinetics and Catalysis Letters
Volume47
Issue number2
DOIs
Publication statusPublished - Jul 1992

Fingerprint

Antimony
Tin
butenes
mixed oxides
Dehydrogenation
dehydrogenation
antimony
Butenes
Oxides
tin
promotion
products
butadiene
Isomerization
Butadiene
isomerization
catalysts
Oxidation
oxidation
Catalysts

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

@article{da477b7eb63b41c4957f4d42ed851d7b,
title = "Oxidative dehydrogenation of n-butenes: Product effect in the reactions over tin-antimony mixed oxides",
abstract = "The addition of possible oxidation and/or isomerization products (butadiene, water, isomeric n-butenes) resulted in neither promotion nor inhibition in the oxidative dehydrogenation of n-butenes over tin-antimony mixed oxide catalysts. On the basis of these and other information on the influence of products an interpretation has been given to complete the reaction mechanism more realistic than those based on previous experimental results.",
author = "K. Hern{\'a}di and J. Hal{\'a}sz and K. Varga and P. Fejes",
year = "1992",
month = "7",
doi = "10.1007/BF02137653",
language = "English",
volume = "47",
pages = "221--226",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
issn = "1878-5190",
publisher = "Springer Netherlands",
number = "2",

}

TY - JOUR

T1 - Oxidative dehydrogenation of n-butenes

T2 - Product effect in the reactions over tin-antimony mixed oxides

AU - Hernádi, K.

AU - Halász, J.

AU - Varga, K.

AU - Fejes, P.

PY - 1992/7

Y1 - 1992/7

N2 - The addition of possible oxidation and/or isomerization products (butadiene, water, isomeric n-butenes) resulted in neither promotion nor inhibition in the oxidative dehydrogenation of n-butenes over tin-antimony mixed oxide catalysts. On the basis of these and other information on the influence of products an interpretation has been given to complete the reaction mechanism more realistic than those based on previous experimental results.

AB - The addition of possible oxidation and/or isomerization products (butadiene, water, isomeric n-butenes) resulted in neither promotion nor inhibition in the oxidative dehydrogenation of n-butenes over tin-antimony mixed oxide catalysts. On the basis of these and other information on the influence of products an interpretation has been given to complete the reaction mechanism more realistic than those based on previous experimental results.

UR - http://www.scopus.com/inward/record.url?scp=0026886965&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0026886965&partnerID=8YFLogxK

U2 - 10.1007/BF02137653

DO - 10.1007/BF02137653

M3 - Article

AN - SCOPUS:0026886965

VL - 47

SP - 221

EP - 226

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

SN - 1878-5190

IS - 2

ER -