Oxazepines and thiazepines, XX: CD-spectra of optically active 2-phenyl-2,3-dihydro-1,5-benzothiazepin-4(5 H)-ones and related 3-phenylthio-3-phenyl-propionic acid derivatives, and X-ray diffraction of one phenylethylamide

Maria Ciechanowicz-Rutkowska, Jacek Grochowski, Albert Lévai, Gisbert Puzicha, Pawel Serda, Günther Snatzke

Research output: Contribution to journalArticle

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Abstract

The absolute configuration of (-)-(1′R,3 S)-4 has been determined by X-ray diffraction. The UV- and CD-spectra of the title compound 8 and the intermediates for its synthesis are discussed. The stronger Cotton effects can be explained by application of the exciton theory to the observed CD-couplets. The CD of the lower homologue 9 of known absolute configuration is in full agreement with that of homochirally analogue 8.

Original languageEnglish
Pages (from-to)981-990
Number of pages10
JournalMonatshefte für Chemie Chemical Monthly
Volume120
Issue number11
DOIs
Publication statusPublished - Nov 1989

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Keywords

  • Chiroptical properties
  • Exciton couplets
  • X-Ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

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