Orthorhombic A1C60: A conducting linear alkali fulleride polymer?

S. Pekker, L. Forró, L. Mihály, A. Jánossy

Research output: Contribution to journalArticle

191 Citations (Scopus)

Abstract

We suggest that the orthorhombic phases of the alkali fullerides, o-A1C60 (A=K, Rb, Cs), are linear polyners formed in the solid state at about 400 K by a [2+2] cycloaddition reaction between the fulleride ions of the fcc high temperature phase. The electronic structure of the linear polymers is quasi-one-dimensional.

Original languageEnglish
Pages (from-to)349-352
Number of pages4
JournalSolid State Communications
Volume90
Issue number6
DOIs
Publication statusPublished - 1994

Fingerprint

fullerides
Cycloaddition
Alkalies
Electronic structure
alkalies
Polymers
Ions
conduction
polymers
cycloaddition
electronic structure
solid state
Temperature
ions

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Orthorhombic A1C60 : A conducting linear alkali fulleride polymer? / Pekker, S.; Forró, L.; Mihály, L.; Jánossy, A.

In: Solid State Communications, Vol. 90, No. 6, 1994, p. 349-352.

Research output: Contribution to journalArticle

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