Organometalloidal derivatives of the transition metals. IX. Synthesis and the crystal structure of (η5-C5H5)Fe(CO)2SiMe2-SiPh3

László Párkányi, Keith H. Pannell, Carlos Hernandez

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Reaction of (η5-C5H5)(CO)2FeNa with ClSiMe2-SiPh3 yields (η5-C5H5)-Fe(CO)2SiMe2-SiPh3. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) Å, which is longer by 0.018 Å than that in Me3Si-SiPh3. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) Å.

Original languageEnglish
Pages (from-to)127-132
Number of pages6
JournalJournal of Organometallic Chemistry
Volume252
Issue number2
DOIs
Publication statusPublished - Aug 16 1983

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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