Organic derivatives of tin (II/IV)

Investigation of their structure

L. Szirtes, J. Megyeri, E. Kuzmann, A. Beck

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The structures of tin(II)-oxalate, tin(IV)Na-EDTA and tin(IV)Na8-inositol hexaphosphate were investigated using XRD analysis. Samples were identified using the Mössbauer study, thermal analysis and FTIR spectrometry. The Mössbauer study determined two different oxidation states of tin atoms, and consequently two different tin surroundings in the end products. The tin oxalate was found to be orthorhombic with space group Pnma, a=9.2066(3)Å, b=9.7590(1)Å, c=13.1848(5)Å, V=1184.62Å3 and Z=8. SnNa-EDTA was found to be monoclinic with space group P21/c1, a=10.7544(3)Å, b=10.1455(3)Å, c=16.5130(6)Å, Β=98.59(2)°, V=1781.50(4)Å3 and Z=4. Sn(C6H6Na8O24P6) was found to be amorphous.

Original languageEnglish
Pages (from-to)786-791
Number of pages6
JournalRadiation Physics and Chemistry
Volume80
Issue number7
DOIs
Publication statusPublished - Jul 2011

Fingerprint

tin
ethylenediaminetetraacetic acids
oxalates
inositols
thermal analysis
oxidation
products
spectroscopy
atoms

Keywords

  • FTIR spectrometry
  • Mössbauer analysis
  • Thermal treatment
  • Tin
  • X-ray diffraction

ASJC Scopus subject areas

  • Radiation

Cite this

Organic derivatives of tin (II/IV) : Investigation of their structure. / Szirtes, L.; Megyeri, J.; Kuzmann, E.; Beck, A.

In: Radiation Physics and Chemistry, Vol. 80, No. 7, 07.2011, p. 786-791.

Research output: Contribution to journalArticle

@article{0286e1a7ce904befa81665c572adfc80,
title = "Organic derivatives of tin (II/IV): Investigation of their structure",
abstract = "The structures of tin(II)-oxalate, tin(IV)Na-EDTA and tin(IV)Na8-inositol hexaphosphate were investigated using XRD analysis. Samples were identified using the M{\"o}ssbauer study, thermal analysis and FTIR spectrometry. The M{\"o}ssbauer study determined two different oxidation states of tin atoms, and consequently two different tin surroundings in the end products. The tin oxalate was found to be orthorhombic with space group Pnma, a=9.2066(3){\AA}, b=9.7590(1){\AA}, c=13.1848(5){\AA}, V=1184.62{\AA}3 and Z=8. SnNa-EDTA was found to be monoclinic with space group P21/c1, a=10.7544(3){\AA}, b=10.1455(3){\AA}, c=16.5130(6){\AA}, Β=98.59(2)°, V=1781.50(4){\AA}3 and Z=4. Sn(C6H6Na8O24P6) was found to be amorphous.",
keywords = "FTIR spectrometry, M{\"o}ssbauer analysis, Thermal treatment, Tin, X-ray diffraction",
author = "L. Szirtes and J. Megyeri and E. Kuzmann and A. Beck",
year = "2011",
month = "7",
doi = "10.1016/j.radphyschem.2010.12.009",
language = "English",
volume = "80",
pages = "786--791",
journal = "Radiation Physics and Chemistry",
issn = "0969-806X",
publisher = "Elsevier Limited",
number = "7",

}

TY - JOUR

T1 - Organic derivatives of tin (II/IV)

T2 - Investigation of their structure

AU - Szirtes, L.

AU - Megyeri, J.

AU - Kuzmann, E.

AU - Beck, A.

PY - 2011/7

Y1 - 2011/7

N2 - The structures of tin(II)-oxalate, tin(IV)Na-EDTA and tin(IV)Na8-inositol hexaphosphate were investigated using XRD analysis. Samples were identified using the Mössbauer study, thermal analysis and FTIR spectrometry. The Mössbauer study determined two different oxidation states of tin atoms, and consequently two different tin surroundings in the end products. The tin oxalate was found to be orthorhombic with space group Pnma, a=9.2066(3)Å, b=9.7590(1)Å, c=13.1848(5)Å, V=1184.62Å3 and Z=8. SnNa-EDTA was found to be monoclinic with space group P21/c1, a=10.7544(3)Å, b=10.1455(3)Å, c=16.5130(6)Å, Β=98.59(2)°, V=1781.50(4)Å3 and Z=4. Sn(C6H6Na8O24P6) was found to be amorphous.

AB - The structures of tin(II)-oxalate, tin(IV)Na-EDTA and tin(IV)Na8-inositol hexaphosphate were investigated using XRD analysis. Samples were identified using the Mössbauer study, thermal analysis and FTIR spectrometry. The Mössbauer study determined two different oxidation states of tin atoms, and consequently two different tin surroundings in the end products. The tin oxalate was found to be orthorhombic with space group Pnma, a=9.2066(3)Å, b=9.7590(1)Å, c=13.1848(5)Å, V=1184.62Å3 and Z=8. SnNa-EDTA was found to be monoclinic with space group P21/c1, a=10.7544(3)Å, b=10.1455(3)Å, c=16.5130(6)Å, Β=98.59(2)°, V=1781.50(4)Å3 and Z=4. Sn(C6H6Na8O24P6) was found to be amorphous.

KW - FTIR spectrometry

KW - Mössbauer analysis

KW - Thermal treatment

KW - Tin

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=79955036630&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79955036630&partnerID=8YFLogxK

U2 - 10.1016/j.radphyschem.2010.12.009

DO - 10.1016/j.radphyschem.2010.12.009

M3 - Article

VL - 80

SP - 786

EP - 791

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

SN - 0969-806X

IS - 7

ER -