Optical properties of the charge transfer salts of tetrathiotetracene

K. Kamarás, G. Grüner

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Powder optical absorption spectra of various tetrathiotetracene (TTT) salts are reported together with solution spectra of neutral and ionized TTT and TTT dimers. Intramolecular transitions are identified by comparing the solid state and solution spectra. The Coulomb correlation energy corresponding to charge fluctuation to TTT is 0.7 eV, independent of stoichiometry and of solid state properties. Complex TTT salts have a low lying optical excitation due to a transition between ionized and neutral molecules.

Original languageEnglish
Pages (from-to)277-281
Number of pages5
JournalSolid State Communications
Volume30
Issue number5
DOIs
Publication statusPublished - May 1979

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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