The reaction of 5‐amino‐1,2,4‐triazoles 1 with carbon disulfide and alkylating agents in basic condition to yield alkyl, aralkyl and aryl (5‐amino‐3‐Q‐1,2,4‐triazol‐1‐yl)dithiocarbonates 2 and alkyl (3‐Q‐1,2,4‐triazol‐5‐yl‐amino)dithiocarbonates 3 was studied. The isomeric and tautomeric structure of derivatives obtained was proved with the help of their uv, pmr and cmr spectra using model compounds prepared for this purpose. The results obtained enabled us to correct some confusion in the literature.
ASJC Scopus subject areas
- Organic Chemistry