On triazoles. XXI. Synthesis of 1,2,4‐triazolyldithiocarbonates

László Pongó, József Reiter, József Barkóczy, P. Sohár, István Pallagi

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Abstract

The reaction of 5‐amino‐1,2,4‐triazoles 1 with carbon disulfide and alkylating agents in basic condition to yield alkyl, aralkyl and aryl (5‐amino‐3‐Q‐1,2,4‐triazol‐1‐yl)dithiocarbonates 2 and alkyl (3‐Q‐1,2,4‐triazol‐5‐yl‐amino)dithiocarbonates 3 was studied. The isomeric and tautomeric structure of derivatives obtained was proved with the help of their uv, pmr and cmr spectra using model compounds prepared for this purpose. The results obtained enabled us to correct some confusion in the literature.

Original languageEnglish
Pages (from-to)1249-1257
Number of pages9
JournalJournal of Heterocyclic Chemistry
Volume27
Issue number5
DOIs
Publication statusPublished - 1990

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ASJC Scopus subject areas

  • Organic Chemistry

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