On triazoles XLVI [1]. Synthesis of 1,3a,5,6,10c-pentaazaacephenanthrylenes

Gábor Berecz, L. Párkányí, A. Kálmán, József Reiter

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5 Citations (Scopus)

Abstract

A novel route to the synthesis of 6,7,8,9-tetrahydro-[1,2,4]triazolo[5,1-b]quinazoline derivatives 4 through 5 and 6 was elaborated. During the synthesis of derivatives 6 novel type tetracyclic 2,3,7,8,9,10-hexahydro1,3a,5,6,10c-pentaazaacephenanthrylenes 9 were formed as by-products. Their structure was proved by spectroscopic methods and by X-ray diffraction spectra. There were also elaborated direct synthetic routes to derivatives 9. Unexpectedly, the S-alkyl groups of derivatives 9 could be easily replaced by different amines, which is contrary to all our previous results. Possible explanations to this enhanced reactivity are given.

Original languageEnglish
Pages (from-to)703-718
Number of pages16
JournalJournal of Heterocyclic Chemistry
Volume39
Issue number4
Publication statusPublished - Jul 2002

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Triazoles
Derivatives
Quinazolines
Amines
Byproducts
X ray diffraction

ASJC Scopus subject areas

  • Organic Chemistry

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On triazoles XLVI [1]. Synthesis of 1,3a,5,6,10c-pentaazaacephenanthrylenes. / Berecz, Gábor; Párkányí, L.; Kálmán, A.; Reiter, József.

In: Journal of Heterocyclic Chemistry, Vol. 39, No. 4, 07.2002, p. 703-718.

Research output: Contribution to journalArticle

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