ON THE USE OF ION-SELECTIVE ELECTRODES FOR MONITORING OSCILLATING REACTIONS - 1. POTENTIAL RESPONSE OF THE SILVER HALIDE MEMBRANE ELECTRODES TO HYPOHALOUS ACIDS.

Z. Noszticzius, E. Nosticzius, Z. A. Schelly

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

The potential reponse of halide ion selective (AgCl, AgBr, and AgI membrane) electrodes to hypohalous acids (HOCl, HOBr, and H//2OI** plus ) is investigated under experimental conditions prevailing in oscillating reactions, i. e. , at H//2SO//4 concentrations of 0. 15 and 1. 5 M. Hypohalous acids are known intermediates in these reactions. The two current theories, the kinetic buffer theory (KBT) and the corrosion potential theory (CPT), of the potential response for halide in concentrations left bracket X** minus right bracket below the solubility (i. e. , where left bracket X** minus right bracket less than K//s** one-half ) are compared. Experimental rsults results are presented which clearly contradict KBT and confirm CPT. New methods of synthesis for silver-free HOBr and silver-free HOI, and a method of quantitative determination of H//2OI** plus beside IO//3** minus , are described.

Original languageEnglish
Pages (from-to)6194-6199
Number of pages6
JournalJournal of the American Chemical Society
Volume104
Issue number23
Publication statusPublished - Jan 1 1982

Fingerprint

Ion-Selective Electrodes
Silver halides
Corrosion
Silver
Buffers
Electrodes
Membranes
Kinetics
Acids
Monitoring
Solubility
Ions
hypobromous acid
hypoiodous acid

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{265ee3619c294e9088b64b91bb65c982,
title = "ON THE USE OF ION-SELECTIVE ELECTRODES FOR MONITORING OSCILLATING REACTIONS - 1. POTENTIAL RESPONSE OF THE SILVER HALIDE MEMBRANE ELECTRODES TO HYPOHALOUS ACIDS.",
abstract = "The potential reponse of halide ion selective (AgCl, AgBr, and AgI membrane) electrodes to hypohalous acids (HOCl, HOBr, and H//2OI** plus ) is investigated under experimental conditions prevailing in oscillating reactions, i. e. , at H//2SO//4 concentrations of 0. 15 and 1. 5 M. Hypohalous acids are known intermediates in these reactions. The two current theories, the kinetic buffer theory (KBT) and the corrosion potential theory (CPT), of the potential response for halide in concentrations left bracket X** minus right bracket below the solubility (i. e. , where left bracket X** minus right bracket less than K//s** one-half ) are compared. Experimental rsults results are presented which clearly contradict KBT and confirm CPT. New methods of synthesis for silver-free HOBr and silver-free HOI, and a method of quantitative determination of H//2OI** plus beside IO//3** minus , are described.",
author = "Z. Noszticzius and E. Nosticzius and Schelly, {Z. A.}",
year = "1982",
month = "1",
day = "1",
language = "English",
volume = "104",
pages = "6194--6199",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "23",

}

TY - JOUR

T1 - ON THE USE OF ION-SELECTIVE ELECTRODES FOR MONITORING OSCILLATING REACTIONS - 1. POTENTIAL RESPONSE OF THE SILVER HALIDE MEMBRANE ELECTRODES TO HYPOHALOUS ACIDS.

AU - Noszticzius, Z.

AU - Nosticzius, E.

AU - Schelly, Z. A.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - The potential reponse of halide ion selective (AgCl, AgBr, and AgI membrane) electrodes to hypohalous acids (HOCl, HOBr, and H//2OI** plus ) is investigated under experimental conditions prevailing in oscillating reactions, i. e. , at H//2SO//4 concentrations of 0. 15 and 1. 5 M. Hypohalous acids are known intermediates in these reactions. The two current theories, the kinetic buffer theory (KBT) and the corrosion potential theory (CPT), of the potential response for halide in concentrations left bracket X** minus right bracket below the solubility (i. e. , where left bracket X** minus right bracket less than K//s** one-half ) are compared. Experimental rsults results are presented which clearly contradict KBT and confirm CPT. New methods of synthesis for silver-free HOBr and silver-free HOI, and a method of quantitative determination of H//2OI** plus beside IO//3** minus , are described.

AB - The potential reponse of halide ion selective (AgCl, AgBr, and AgI membrane) electrodes to hypohalous acids (HOCl, HOBr, and H//2OI** plus ) is investigated under experimental conditions prevailing in oscillating reactions, i. e. , at H//2SO//4 concentrations of 0. 15 and 1. 5 M. Hypohalous acids are known intermediates in these reactions. The two current theories, the kinetic buffer theory (KBT) and the corrosion potential theory (CPT), of the potential response for halide in concentrations left bracket X** minus right bracket below the solubility (i. e. , where left bracket X** minus right bracket less than K//s** one-half ) are compared. Experimental rsults results are presented which clearly contradict KBT and confirm CPT. New methods of synthesis for silver-free HOBr and silver-free HOI, and a method of quantitative determination of H//2OI** plus beside IO//3** minus , are described.

UR - http://www.scopus.com/inward/record.url?scp=0020204708&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0020204708&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0020204708

VL - 104

SP - 6194

EP - 6199

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 23

ER -