On the Two Pathways of Cyclohexane Dehydrogenation

P. Tétényi, Z. Paál, M. Dobrovolszky

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Dehydrogenation of 1:1 mixture of cyclohexane-[14C] plus cyclohexene was studied over six carrier-free VIIIB metals as catalysts with formation of cyclohexene intermediate being evaluated by comparing specific radioactivities of cyclohexene and benzene. Close values were found for cobalt and nickel, whereas the specific radioactivity of benzene was higher for iridium, rhodium, palladium and platinum. Results were interpreted in terms of the existence of two different pathways of cyclohexane dehydrogenation involving 1,2- and 1,3-diadsorbed surface species, respectively; with only the former being able to produce cyclohexene. The ratio of the two mechanisms can be correlated with the atomic diameter of the metal, smaller atoms favouring 1,2-adsorption.

Original languageEnglish
Pages (from-to)267-278
Number of pages12
JournalZeitschrift fur Physikalische Chemie
Volume102
Issue number5-6
DOIs
Publication statusPublished - Oct 1976

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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