On the Structural Differences between Trifluoromethyl Sulphonyl Chloride (CF3SO2Cl) and Methane Sulphonyl Chloride (CH3SO2Cl)

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Abstract

CNDO/2 MO calculations show the elektron withdrawing ability of the CF3 group versus the electron releasing of the CH3 group to be the primary source of the considerable S-C bond lengthening in CF3SO2Cl as compared with CH3SO2Cl.

Original languageEnglish
Pages (from-to)911-913
Number of pages3
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume34
Issue number7
DOIs
Publication statusPublished - Jul 1 1979

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Methane
Chlorides
methane
chlorides
Electrons
releasing
Electron
electrons

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Mathematical Physics
  • Physics and Astronomy(all)

Cite this

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title = "On the Structural Differences between Trifluoromethyl Sulphonyl Chloride (CF3SO2Cl) and Methane Sulphonyl Chloride (CH3SO2Cl)",
abstract = "CNDO/2 MO calculations show the elektron withdrawing ability of the CF3 group versus the electron releasing of the CH3 group to be the primary source of the considerable S-C bond lengthening in CF3SO2Cl as compared with CH3SO2Cl.",
author = "I. Mayer and I. Hargittai",
year = "1979",
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