On the molecular structure of (CH3)2NSO2N(CH3)2 as studied by gas electron diffraction

I. Hargittai, Erzsébet Vajda, Annamária Szöke

Research output: Contribution to journalArticle

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Abstract

The following bond lengths and bond angles have been deduced from a vapour phase electron diffraction study of (CH3)2NSO2N(CH3)2: r(C-H) 1.114 ± 0.005 Å, r(S-O) 1.432 ± 0.010 Å, r(N-C) 1.475 ± 0.013 Å, r(S-N) 1.651 ± 0.003 Å, ∠N-C-H 109.3 ± 2.0°, ∠C-N-C 118.0 ± 302°, ∠S-N-C 115.2 ± 1.1°, ∠N-S-N 110.5±1.3° and ∠O-S-O 114.7±2.5°. The sulphur bond configuration and the prevailing conformation, which was identical to that in the crystal, are discussed in relation to analogous sulphide and sulphoxide derivatives.

Original languageEnglish
Pages (from-to)381-390
Number of pages10
JournalJournal of Molecular Structure
Volume18
Issue number3
DOIs
Publication statusPublished - 1973

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Bond length
Sulfides
Molecular Structure
Sulfur
Electron diffraction
Molecular structure
Conformations
sulfides
molecular structure
sulfur
electron diffraction
Gases
Vapors
Electrons
vapor phases
Derivatives
Crystals
configurations
gases
crystals

ASJC Scopus subject areas

  • Structural Biology
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Materials Science (miscellaneous)
  • Atomic and Molecular Physics, and Optics

Cite this

On the molecular structure of (CH3)2NSO2N(CH3)2 as studied by gas electron diffraction. / Hargittai, I.; Vajda, Erzsébet; Szöke, Annamária.

In: Journal of Molecular Structure, Vol. 18, No. 3, 1973, p. 381-390.

Research output: Contribution to journalArticle

Hargittai, I. ; Vajda, Erzsébet ; Szöke, Annamária. / On the molecular structure of (CH3)2NSO2N(CH3)2 as studied by gas electron diffraction. In: Journal of Molecular Structure. 1973 ; Vol. 18, No. 3. pp. 381-390.
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abstract = "The following bond lengths and bond angles have been deduced from a vapour phase electron diffraction study of (CH3)2NSO2N(CH3)2: r(C-H) 1.114 ± 0.005 {\AA}, r(S-O) 1.432 ± 0.010 {\AA}, r(N-C) 1.475 ± 0.013 {\AA}, r(S-N) 1.651 ± 0.003 {\AA}, ∠N-C-H 109.3 ± 2.0°, ∠C-N-C 118.0 ± 302°, ∠S-N-C 115.2 ± 1.1°, ∠N-S-N 110.5±1.3° and ∠O-S-O 114.7±2.5°. The sulphur bond configuration and the prevailing conformation, which was identical to that in the crystal, are discussed in relation to analogous sulphide and sulphoxide derivatives.",
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AB - The following bond lengths and bond angles have been deduced from a vapour phase electron diffraction study of (CH3)2NSO2N(CH3)2: r(C-H) 1.114 ± 0.005 Å, r(S-O) 1.432 ± 0.010 Å, r(N-C) 1.475 ± 0.013 Å, r(S-N) 1.651 ± 0.003 Å, ∠N-C-H 109.3 ± 2.0°, ∠C-N-C 118.0 ± 302°, ∠S-N-C 115.2 ± 1.1°, ∠N-S-N 110.5±1.3° and ∠O-S-O 114.7±2.5°. The sulphur bond configuration and the prevailing conformation, which was identical to that in the crystal, are discussed in relation to analogous sulphide and sulphoxide derivatives.

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