On the kinetics of the transition metal catalyzed decomposition of secondary hydroperoxides

I. P. Hajdu, I. Nemes, L. Sümegi, T. Vidóczy, D. Gál

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A general mechanism was proposed for the title reactions which describes the kinetics of hydroperoxide decomposition as well as product accumulation throughout the whole reaction period in an analytical form. The following catalytic steps were included: (Formula Presented.) where the deactivation takes place as a result of radical–catalyst interaction inside the cage. The resulting equations give satisfactory description of the literature data in the case of various catalysts and hydroperoxides.

Original languageEnglish
Pages (from-to)1191-1202
Number of pages12
JournalInternational Journal of Chemical Kinetics
Volume13
Issue number11
DOIs
Publication statusPublished - 1981

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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