On the interaction of hydroperoxide and inhibitor molecules

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Decomposition of 1‐phenylethyl‐hydroperoxide has been studied in the presence of 2,6‐di‐tert‐butyl‐4‐methyl‐phenol inhibitor in ethylbenzene and chlorobenzene both in oxygen and nitrogen. The oxygen consumption and the inhibitor concentrations were measured against the initial inhibitor concentrations. Two methods were applied for the determination of the rate coefficients of the reaction: (Formula Presented.) Its value is about 3 × 10−4L × mol−1 × S−1, at 120°C. However, large experimental errors we deal with, the existence of a reaction yielding radicals, presumably an interaction between hydroperoxide and inhibitor molecules, can be established emphasizing the importance of measurements carried out with various initial concentrations of the inhibitor.

Original languageEnglish
Pages (from-to)271-275
Number of pages5
JournalInternational Journal of Chemical Kinetics
Volume17
Issue number3
DOIs
Publication statusPublished - 1985

Fingerprint

Oxygen Consumption
inhibitors
Hydrogen Peroxide
Nitrogen
Oxygen
Molecules
molecules
interactions
Decomposition
oxygen consumption
chlorobenzenes
chlorobenzene
ethylbenzene
decomposition
nitrogen
oxygen
coefficients

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

On the interaction of hydroperoxide and inhibitor molecules. / Heberger, K.

In: International Journal of Chemical Kinetics, Vol. 17, No. 3, 1985, p. 271-275.

Research output: Contribution to journalArticle

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