Observation of the ν6 + ν9 Band of Ketene via Resonant Coriolis Interaction with ν8

Martin Gruebele, John W.C. Johns, László Nemes

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Abstract

We observed and analyzed a b-axis Coriolis resonance between higher J states of the ν6 + ν9 combination band and the ν8 fundamental of ketene in the spectral region 940-970 cm-1. The interaction resonantly couples Ka = 1 states of the combination band to Ka = 0 states of the fundamental and also affects Ka = 1, 2 states in the fundamental. Due to the involvement of strongly asymmetry-split low K levels, the rotational constants and band origin of ν6 + ν9 could be accurately determined and are discussed in the light of high-quality anharmonic force fields. The Coriolis coupling parameter, ζb8,6+9, is very precisely determined. A smaller perturbation, which could not be fully analyzed, is tentatively attributed to Ka = 2 upper states in the ν5 + ν9 band.

Original languageEnglish
Pages (from-to)376-380
Number of pages5
JournalJournal of Molecular Spectroscopy
Volume198
Issue number2
DOIs
Publication statusPublished - Dec 1999

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ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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