Novel self-assemblies of oppositely charged polyelectrolytes and surfactants in the presence of neutral polymer

Katalin Pojják, R. Mészáros

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In this Letter, the effect of addition of poly(ethylene oxide) (PEO) on the nature of the self-assemblies of sodium dodecyl sulfate (SDS) and branched poly(ethyleneimine) (PEI) is investigated. We demonstrate that the neutral polymer adsorbs onto the surface of the polyelectrolyte/surfactant nanoparticles, which may result in sterically stabilized colloidal dispersions of the nanoparticles with hydrophobic core and hydrophilic corona. The kinetic stability is maintained even at high ionic strengths, where the charge stabilization of the PEI/SDS dispersions is inefficient. These results might be exploited to improve the efficiency of those formulations, which containoppositely charged macromolecules and amphiphiles.

Original languageEnglish
Pages (from-to)13336-13339
Number of pages4
JournalLangmuir
Volume25
Issue number23
DOIs
Publication statusPublished - Dec 1 2009

Fingerprint

Sodium dodecyl sulfate
Polyethylene oxides
Polyelectrolytes
sodium sulfates
Dispersions
Surface-Active Agents
Sodium Dodecyl Sulfate
Self assembly
self assembly
Polymers
Surface active agents
surfactants
Nanoparticles
nanoparticles
Amphiphiles
polymers
ethylene oxide
Ionic strength
Macromolecules
macromolecules

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy

Cite this

Novel self-assemblies of oppositely charged polyelectrolytes and surfactants in the presence of neutral polymer. / Pojják, Katalin; Mészáros, R.

In: Langmuir, Vol. 25, No. 23, 01.12.2009, p. 13336-13339.

Research output: Contribution to journalArticle

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