Novel reactions with hetaryldieneamines as activated olefins

A. Messmer, Gy Hajós, G. Timári, A. Gelléri

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In the presence of appropriate reagents, hetaryldieneamines were found to react with only one of their two double bonds. Reaction with aryldiazonium salts resulted in hydrazone 2 while azodicarboxylic ester afforded substitution product 3. In reactions with benzofuroxan and arylazides, hetaryldieneamines reacted as enamines to yield quinoxaline (4) and v-triazole derivatives (5), respectively.

Original languageEnglish
Pages (from-to)1121-1124
Number of pages4
JournalMonatshefte für Chemie Chemical Monthly
Volume119
Issue number10
DOIs
Publication statusPublished - Oct 1 1988

Keywords

  • Cycloaddition
  • Diels Alder reaction of inverse electron demand
  • Dieneamine

ASJC Scopus subject areas

  • Chemistry(all)

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