Novel reactions of spirosulfurane precursor sulfides and sulfoxides

M. Kuti, J. Rábai, I. Kapovits

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4 Citations (Scopus)

Abstract

The S1V(C, C, N, 0] spirosulfurane 19 and the lactam-sulfoxides 21, 22 and 23 with seven-, eight- and nine-membered rings have been prepared by oxidation and dehydration of trifluoroacetylaminoaryl-carboxyphenyl sulfides and sulfoxides, respectively. A mechanism is proposed for the formations of lactam-sulfoxides. The preparation of the starting sulfides and sulfoxides is also described.

Original languageEnglish
Pages (from-to)119-127
Number of pages9
JournalPhosphorus, Sulfur, and Silicon and the Related Elements
Volume85
Issue number1-4
DOIs
Publication statusPublished - Dec 1 1993

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Keywords

  • Diaryl sulfides
  • carboxyl activation
  • diaryl sulfoxides
  • lactam-sulfoxide formation
  • lactams
  • spirosulfurane

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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