Novel Platinum(II) - Complexes Incorporating Optically Active P-Heterocycles as the Ligands

Péter Bagi, Tamara Kovács, L. Kollár, E. Fogassy, G. Keglevich

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

(Chemical Equation Presented). Several 5- and 6-membered P-heterocycles were made available in optically active form by resolution applying TADDOL-derivatives, as well as the Ca2+ salts of the dibenzoyl- and di-p-toluoyl-tartaric acid as the resolving agents. The optically active 3-phospholene oxides were converted to the corresponding platinum-complexes that were used as catalysts in the hydroformylation of styrene and they showed interesting selectivities.

Original languageEnglish
Pages (from-to)821-823
Number of pages3
JournalPhosphorus, Sulfur and Silicon and Related Elements
Volume190
Issue number5-6
DOIs
Publication statusPublished - Jun 3 2015

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Hydroformylation
Styrene
Platinum
Oxides
Salts
Ligands
Derivatives
Catalysts
tartaric acid

Keywords

  • 3-Phospholene oxide
  • catalyst precursor
  • hydroformylation
  • optical resolution
  • platinum complex

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

Novel Platinum(II) - Complexes Incorporating Optically Active P-Heterocycles as the Ligands. / Bagi, Péter; Kovács, Tamara; Kollár, L.; Fogassy, E.; Keglevich, G.

In: Phosphorus, Sulfur and Silicon and Related Elements, Vol. 190, No. 5-6, 03.06.2015, p. 821-823.

Research output: Contribution to journalArticle

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