Novel organic-inorganic nanohybrids based on poly(N,N-dimethyl acrylamide)-1-polyisobutylene amphiphilic polymer conetworks

Péter Mezey, Attila Domján, Béla Iván, Ralf Thomann, Rolf Mülhaupt

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

A series of poly(N,N-dimethylacrylamide)-/-polyisobutylene (PDMAAm-l-PIB) amphiphilic conetworks were synthesized from two incompatible polymers, i.e. hydrophilic PDMAAm and strongly hydrophobic PIB in a wide range of composition (38-80 m/m % PIB). Swelling experiments were carried out to determine the equilibrium swelling ratios which proved the amphiphilic nature of these new materials, and are in correlation with composition. Thermal analysis (DSC), small angle X-ray scattering (SAXS) and atomic force microscopy (AFM) measurements were carried out. Results show special phase separated morphology, where the size of the phases are in the nanometer range in all cases. Furthermore, the nanophases of the conetworks have composition dependent spatial arrangement. Successful synthesis of silver nanoparticles was achived inside of the conetwork's hydrophilic phases resulting in a novel organic-inorganic nanohybrid material.

Original languageEnglish
Title of host publicationTechnical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008
Pages715-718
Number of pages4
Volume2
Publication statusPublished - 2008
Event2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008 - Quebec City, QC, United States
Duration: Jun 1 2008Jun 5 2008

Other

Other2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008
CountryUnited States
CityQuebec City, QC
Period6/1/086/5/08

Fingerprint

Swelling
Polymers
Chemical analysis
X ray scattering
Thermoanalysis
Atomic force microscopy
Silver
Nanoparticles
Experiments

Keywords

  • Amphiphilic
  • Conetwork
  • Hydrogel
  • Nanoparticle
  • Silver

ASJC Scopus subject areas

  • Mechanical Engineering

Cite this

Mezey, P., Domján, A., Iván, B., Thomann, R., & Mülhaupt, R. (2008). Novel organic-inorganic nanohybrids based on poly(N,N-dimethyl acrylamide)-1-polyisobutylene amphiphilic polymer conetworks. In Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008 (Vol. 2, pp. 715-718)

Novel organic-inorganic nanohybrids based on poly(N,N-dimethyl acrylamide)-1-polyisobutylene amphiphilic polymer conetworks. / Mezey, Péter; Domján, Attila; Iván, Béla; Thomann, Ralf; Mülhaupt, Rolf.

Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. Vol. 2 2008. p. 715-718.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Mezey, P, Domján, A, Iván, B, Thomann, R & Mülhaupt, R 2008, Novel organic-inorganic nanohybrids based on poly(N,N-dimethyl acrylamide)-1-polyisobutylene amphiphilic polymer conetworks. in Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. vol. 2, pp. 715-718, 2008 NSTI Nanotechnology Conference and Trade Show, NSTI Nanotech 2008 Joint Meeting, Nanotechnology 2008, Quebec City, QC, United States, 6/1/08.
Mezey P, Domján A, Iván B, Thomann R, Mülhaupt R. Novel organic-inorganic nanohybrids based on poly(N,N-dimethyl acrylamide)-1-polyisobutylene amphiphilic polymer conetworks. In Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. Vol. 2. 2008. p. 715-718
Mezey, Péter ; Domján, Attila ; Iván, Béla ; Thomann, Ralf ; Mülhaupt, Rolf. / Novel organic-inorganic nanohybrids based on poly(N,N-dimethyl acrylamide)-1-polyisobutylene amphiphilic polymer conetworks. Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, NSTI-Nanotech, Nanotechnology 2008. Vol. 2 2008. pp. 715-718
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