Novel fluorescent isoquinoline derivatives obtained via Buchwald-Hartwig coupling of isoquinolin-3-amines

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3 Citations (Scopus)

Abstract

Isoquinolin-3-amines bearing an alkyl group or hydrogen atom in position 4 easily underwent Buchwald-Hartwig coupling reactions with various substituted aryl halides. Investigation of the selected new derivatives with fluorescent spectroscopy revealed that the reaction products have similar photophysical properties to those of isoquinolin-3-amine except the N-(nitrophenyl) derivatives, which emit negligible fluorescence.

Original languageEnglish
Pages (from-to)109-119
Number of pages11
JournalArkivoc
Volume2012
Issue number5
DOIs
Publication statusPublished - Jan 24 2012

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Amines
Bearings (structural)
Derivatives
Reaction products
Hydrogen
Fluorescence
Spectroscopy
Atoms
isoquinoline

Keywords

  • Buchwald-Hartwig amination
  • Fluorescence
  • Isoquinolinamine
  • Pyridinamine

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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title = "Novel fluorescent isoquinoline derivatives obtained via Buchwald-Hartwig coupling of isoquinolin-3-amines",
abstract = "Isoquinolin-3-amines bearing an alkyl group or hydrogen atom in position 4 easily underwent Buchwald-Hartwig coupling reactions with various substituted aryl halides. Investigation of the selected new derivatives with fluorescent spectroscopy revealed that the reaction products have similar photophysical properties to those of isoquinolin-3-amine except the N-(nitrophenyl) derivatives, which emit negligible fluorescence.",
keywords = "Buchwald-Hartwig amination, Fluorescence, Isoquinolinamine, Pyridinamine",
author = "J{\'o}zsef Balog and Zsuzsanna Riedl and Gy{\"o}rgy Haj{\'o}s and Zsombor Miskolczy and L{\'a}szl{\'o} Bicz{\'o}k",
year = "2012",
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doi = "10.3998/ark.5550190.0013.511",
language = "English",
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T1 - Novel fluorescent isoquinoline derivatives obtained via Buchwald-Hartwig coupling of isoquinolin-3-amines

AU - Balog, József

AU - Riedl, Zsuzsanna

AU - Hajós, György

AU - Miskolczy, Zsombor

AU - Biczók, László

PY - 2012/1/24

Y1 - 2012/1/24

N2 - Isoquinolin-3-amines bearing an alkyl group or hydrogen atom in position 4 easily underwent Buchwald-Hartwig coupling reactions with various substituted aryl halides. Investigation of the selected new derivatives with fluorescent spectroscopy revealed that the reaction products have similar photophysical properties to those of isoquinolin-3-amine except the N-(nitrophenyl) derivatives, which emit negligible fluorescence.

AB - Isoquinolin-3-amines bearing an alkyl group or hydrogen atom in position 4 easily underwent Buchwald-Hartwig coupling reactions with various substituted aryl halides. Investigation of the selected new derivatives with fluorescent spectroscopy revealed that the reaction products have similar photophysical properties to those of isoquinolin-3-amine except the N-(nitrophenyl) derivatives, which emit negligible fluorescence.

KW - Buchwald-Hartwig amination

KW - Fluorescence

KW - Isoquinolinamine

KW - Pyridinamine

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U2 - 10.3998/ark.5550190.0013.511

DO - 10.3998/ark.5550190.0013.511

M3 - Article

AN - SCOPUS:84871857014

VL - 2012

SP - 109

EP - 119

JO - Arkivoc

JF - Arkivoc

SN - 1551-7012

IS - 5

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