Novel fluorescent isoquinoline derivatives obtained via Buchwald-Hartwig coupling of isoquinolin-3-amines

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Abstract

Isoquinolin-3-amines bearing an alkyl group or hydrogen atom in position 4 easily underwent Buchwald-Hartwig coupling reactions with various substituted aryl halides. Investigation of the selected new derivatives with fluorescent spectroscopy revealed that the reaction products have similar photophysical properties to those of isoquinolin-3-amine except the N-(nitrophenyl) derivatives, which emit negligible fluorescence.

Original languageEnglish
Pages (from-to)109-119
Number of pages11
JournalArkivoc
Volume2012
Issue number5
DOIs
Publication statusPublished - Jan 24 2012

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Keywords

  • Buchwald-Hartwig amination
  • Fluorescence
  • Isoquinolinamine
  • Pyridinamine

ASJC Scopus subject areas

  • Organic Chemistry

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